Not really. It probably just depends on the situation. I know there have been stories where Spidey and Wolverine have fought one on one. In some cases, Spidey wins. In others, it's a draw. I think Wolverine did win ONCE. In this particular situation, the deal was that they weren't taking him seriously. I don't remember the specifics of WHY, but the groups that the Beyonder had transported split into three factions: Mutant, 'other' hero, and villain. Spider-Man wanted to ask Xavier about something. When the X-team wouldn't let him, he barrelled through them. They TRIED to stop him, but the truth is that he's just to fast for them. I'm sure if Nightcrawler or Quicksilver had been there, they could have possibly slowed him down enough to let Cyclops blast him.
Sometimes being outnumbered is an impetus to fight your best, and sometimes being in the group that outnumbers causes overconfidence, which can be detrimental. (After all, you are talking about a guy who had to fight several TEAMS of villains -- not the least of which was the Sinister Six in various incarnations -- alone. And win.)
One thing about Hero-on-Hero battles is that they have to end rather quickly, or someone would get seriously hurt. Again, speaking of the Secret Wars fight, if it had been allowed to go longer, Spidey would likely have tired to the point where the X-guys could overpower him. To me, Spidey "won" the fight because they never touched him once. He, on the other hand, was quite the nuisance with his webbing, and I think he even had to smack Cyclops around a little. (It's been ages since I read this story, but the "outcome" sticks out in my mind because of how many people always tried to tell me how much better the X-Men were than Spidey. "Well, if that's the case, how'd THIS happen??" Oh well.)
Tangentally, since the subject of Batman's origins popped up: Have you ever noticed that many of our super heroes have tragic pasts? Batman became a vigilante because his parents were killed in front of him as a boy. The drive that evil_d spoke of came from his desire that what he experienced would not happen to anyone else. He then took in Dick Grayson and trained him because it *did* happen again, and he felt he was in the unique position to understand. Peter Parker, who was bitten by that spider, tried to use his new powers for fame, but because he didn't use them to stop a bad guy, his dear uncle, who was like a father to him, was murdered. "With great power comes great responsibility." I love that phrase.
Superman came from a doomed world. While his upbringing isn't tragic -- he had very loving "parents" on earth -- his history still has that edge of tragedy to it. Daredevil (whose exploits I've never actually followed, so if I'm wrong, someone PLEASE correct me!) got hit by a bus and lost his sight, but gained a "radar" ability.
Frank Castle (aka The Punisher), who is ALSO not a "super" hero, witnessed his entire family murdered by a gang, I believe, and swore an oath to rid the world of this type of scum. He and Spidey have crossed paths a few times. They're not friends.
Even the TransFormers, since kramer brought them up -- they've been engaged in a civil war for billions and billions of years, and are still fighting today in Dreamwave comics! (Titan is reprinting some of the Marvel issues, and I'm loving re-reading these stories. Volume 5 will reprint some issues of the UK version of the TF comics!)
So much tragedy, and so much good being done with that energy. I *love* comics!!
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This is not my empire.